Pyrosilicate
Appearance
Names | |
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IUPAC name
disiloxane-1,1,1,3,3,3-hexolatato
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Other names
disilicate, diorthosilicate
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
CompTox Dashboard (EPA)
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Properties | |
O7Si2 | |
Molar mass | 168.163 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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A pyrosilicate is a type of chemical compound; either an ionic compound that contains the pyrosilicate anion Si
2O6−
7, or an organic compound with the hexavalent ≡O
3Si-O-SiO
3≡ group. The anion is also called disilicate[1] or diorthosilicate.
Ionic pyrosilicates can be considered salts of the unstable pyrosilicic acid, H
6Si
2O
7. Unlike the acid, the salts can be stable; as in
- sodium pyrosilicate Na
6Si
2O
7, a possible component of water glass. - sodium iron(II) pyrosilicate Na
2Fe
2Si
2O
7, a potential cathode material for batteries.[2] - sodium manganese(II) pyrosilicate Na
2Fe
2Si
2O
7, another potential cathode material.[3][4]
Indeed, pyrosilicates occur widely in nature as a class of silicate minerals, specificlaly the sorosilicates.
References
- ^ "Disilicate". Chemspider website, CSID:5257009, Accessed 2018-05-26
- ^ Abhishek Panigrahi, Shin-ichi Nishimura, Tatau Shimada, Eriko Watanabe, Wenwen Zhao, Gosuke Oyama, and Atsuo Yamada (2017): "Sodium Iron(II) Pyrosilicate Na
2Fe
2Si
2O
7: A Potential Cathode Material in the Na
2O-FeO-{[chem|Si|O|2}} System". Chemistry of Materials, volume 29, issue 10, pages 4361–4366. doi:10.1021/acs.chemmater.7b00764 - ^ Viktor Renman, Mario Valvo, Cheuk-Wai Tai, and Cesar Pay Gómez (2017): "Manganese Pyrosilicates as Novel Positive Electrode Materials for Na-Ion Batteries". Uppsala University Publications, DIVA urn:nbn:se:uu:diva-334063
- ^ Viktor Renman (2017): "Structural and Electrochemical Relations in Electrode Materials for Rechargeable Batteries", Doctoral Thesis, Uppsala University, Department of Chemistry. ORCID: 0000-0001-8739-4054