Kepert model

The Kepert model is a modification of VSEPR theory used to predict the 3-dimensional structures of transitional metal complexes. In the Kepert model, the ligands attached to the metal are considered to repel each other the same way that point charges repel each other in VSEPR theory. Unlike VSEPR theory, the Kepert model does not account for non-bonding electrons. Therefore, the geometry of the coordination complex is independent of the electronic configuration of the metal center. Thus [ML_n]^m+ has the same coordination geometry as [ML_n]^m−. The Kepert model cannot explain the formation of square planar complexes or distorted structures.

The Kepert model predicts the following geometries for coordination numbers of 2 through 8:

2. Linear
3. Trigonal planar
4. Tetrahedral
5. Trigonal bipyramidal or Square pyramidal
6. Octahedral
7. Capped octahedral, Pentagonal bipyramidal or Capped trigonal prismatic
8. Square antiprismatic or Dodecahedral

Reference

Housecroft C.E. and Sharpe A.G. Inorganic Chemistry (2nd ed., Pearson Prentice-Hall 2005) p.541-2 ISBN 0130-39913-2