Intermetallic particle
Appearance
Intermetallic particles form during solidification of metallic alloys.
For example Al-Si-Cu-Mg alloys form Al5FeSi- plate like intermetallic phase, Chinese scipt like -Al8Fe2Si, Al2Cu, etc. The size and morphology of these intermetallic phases in these alloys control the mechanical properties of these alloys especially strength and ductility.[1] The size of these phases depends on the secondary dendrite arm spacing[2], as well as the Si content of the alloy[3][4][5][6][7], of the primary phase in the micro structure.
Phases and crystal Structures
Phase | Structure | Space Group | a | b | c | α | β | γ | .. |
---|---|---|---|---|---|---|---|---|---|
α-Al8Fe2Si[8] | hexagonal | p63/mmc(194) | 12.404 | 12.404 | 26.234 | 90 | 90 | 120 | .. |
β-Al5FeSi[9] | monoclinic | 2/m | 6.16760 | 6.1661 | 20.8093 | .. | .. | 91 | .. |
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In-situ synchrotron diffraction experiment[10] on Electron alloy-WE 43 (Mg4Y3Nd) shows that this alloy form the following intermetallic phases ;Mg12Nd, Mg14Y4Nd,and Mg24Y5.
Phases and crystal Structures
References
- ^ Caceres, C. H. Svensson, I. L. Taylor, J. A. "Strength-ductility behaviour of Al-Si-Cu-Mg casting alloys in T6 temper" (5).
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(help)CS1 maint: multiple names: authors list (link) - ^ Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (9 May 2013). "Alloy Composition and Dendrite Arm Spacing in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 44 (9): 4071–4080. doi:10.1007/s11661-013-1768-x. PMID http://link.springer.com/article/10.1007%2Fs11661-013-1768-x.
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- ^ Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (July 2013). "Effect of Si Content on the Size of Fe-Rich Intermetallic Particles in Al-xSi-0.8Fe Alloys". Materials Science Forum. 765: 107–111. doi:10.4028/www.scientific.net/MSF.765.107.
- ^ http://onlinelibrary.wiley.com/doi/10.1002/9781118888100.ch17/summary.
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(help) - ^ . doi:10.1002/9781118888100.ch17.
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(help) - ^ . doi:10.14264/uql.2015.91.
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(help) - ^ Sivarupan, Tharmalingam; Taylor, John Andrew; Cáceres, Carlos Horacio (25 February 2015). "SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 46 (5): 2082–2107. doi:10.1007/s11661-015-2808-5.
- ^ R.N. Corby and P.J. Black: Acta Crystallogr. Sect. B, 1977, vol. 33, pp. 3468–75.
- ^ V. Hansen, B. Hauback, M. Sundberg, C. Romming, and J. Gjonnes: Acta Crystallogr. Sect. B, 1998, vol. 54, pp. 351–57.
- ^ Tolnai, D.; Mendis, C.L.; Stark, A.; Szakács, G.; Wiese, B.; Kainer, K.U.; Hort, N. (July 2013). "In situ synchrotron diffraction of the solidification of Mg4Y3Nd". Materials Letters. 102–103: 62–64. doi:10.1016/j.matlet.2013.03.110.