Unspecific peroxygenase
Appearance
Unspecific peroxygenase | |||||||||
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Identifiers | |||||||||
EC no. | 1.11.2.1 | ||||||||
Databases | |||||||||
IntEnz | IntEnz view | ||||||||
BRENDA | BRENDA entry | ||||||||
ExPASy | NiceZyme view | ||||||||
KEGG | KEGG entry | ||||||||
MetaCyc | metabolic pathway | ||||||||
PRIAM | profile | ||||||||
PDB structures | RCSB PDB PDBe PDBsum | ||||||||
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Unspecific peroxygenase (EC 1.11.2.1, aromatic peroxygenase, mushroom peroxygenase, haloperoxidase-peroxygenase, Agrocybe aegerita peroxidase) is an enzyme with system name substrate:hydrogen peroxide oxidoreductase (RH-hydroxylating or -epoxidising).[1][2][3][4][5][6][7][8][9] This enzyme catalyses the following chemical reaction
- RH + H2O2 ROH + H2O
Unspecific peroxygenase is a heme-thiolate protein (P450).
References
- ^ Ullrich, R., Nuske, J., Scheibner, K., Spantzel, J. and Hofrichter, M. (2004). "Novel haloperoxidase from the agaric basidiomycete Agrocybe aegerita oxidizes aryl alcohols and aldehydes". Appl. Environ. Microbiol. 70: 4575–4581. PMID 15294788.
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: CS1 maint: multiple names: authors list (link) - ^ Ullrich, R. and Hofrichter, M. (2005). "The haloperoxidase of the agaric fungus Agrocybe aegerita hydroxylates toluene and naphthalene". FEBS Lett. 579: 6247–6250. PMID 16253244.
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: CS1 maint: multiple names: authors list (link) - ^ Anh, D.H., Ullrich, R., Benndorf, D., Svatos, A., Muck, A. and Hofrichter, M. (2007). "The coprophilous mushroom Coprinus radians secretes a haloperoxidase that catalyzes aromatic peroxygenation". Appl. Environ. Microbiol. 73: 5477–5485. PMID 17601809.
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: CS1 maint: multiple names: authors list (link) - ^ Ullrich, R., Dolge, C., Kluge, M. and Hofrichter, M. (2008). "Pyridine as novel substrate for regioselective oxygenation with aromatic peroxygenase from Agrocybe aegerita". FEBS Lett. 582: 4100–4106. PMID 19022254.
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: CS1 maint: multiple names: authors list (link) - ^ Aranda, E., Kinne, M., Kluge, M., Ullrich, R. and Hofrichter, M. (2009). "Conversion of dibenzothiophene by the mushrooms Agrocybe aegerita and Coprinellus radians and their extracellular peroxygenases". Appl. Microbiol. Biotechnol. 82: 1057–1066. PMID 19039585.
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: CS1 maint: multiple names: authors list (link) - ^ Kinne, M., Poraj-Kobielska, M., Aranda, E., Ullrich, R., Hammel, K.E., Scheibner, K. and Hofrichter, M. (2009). "Regioselective preparation of 5-hydroxypropranolol and 4′-hydroxydiclofenac with a fungal peroxygenase". Bioorg. Med. Chem. Lett. 19: 3085–3087. PMID 19394224.
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: CS1 maint: multiple names: authors list (link) - ^ Kluge, M., Ullrich, R., Dolge, C., Scheibner, K. and Hofrichter, M. (2009). "Hydroxylation of naphthalene by aromatic peroxygenase from Agrocybe aegerita proceeds via oxygen transfer from H2O2 and intermediary epoxidation". Appl. Microbiol. Biotechnol. 81: 1071–1076. PMID 18815784.
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: CS1 maint: multiple names: authors list (link) - ^ Kinne, M., Poraj-Kobielska, M., Ralph, S.A., Ullrich, R., Hofrichter, M. and Hammel, K.E. (2009). "Oxidative cleavage of diverse ethers by an extracellular fungal peroxygenase". J. Biol. Chem. 284: 29343–29349. PMID 19713216.
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: CS1 maint: multiple names: authors list (link) - ^ Pecyna, M.J., Ullrich, R., Bittner, B., Clemens, A., Scheibner, K., Schubert, R. and Hofrichter, M. (2009). "Molecular characterization of aromatic peroxygenase from Agrocybe aegerita". Appl. Microbiol. Biotechnol. 84: 885–897. PMID 19434406.
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: CS1 maint: multiple names: authors list (link)
External links
- Unspecific+peroxygenase at the U.S. National Library of Medicine Medical Subject Headings (MeSH)