Leveling effect
Leveling effect or solvent leveling refers to the effect of solvent on the properties of acids and bases. The strength of a strong acid is limited ("leveled") by the basicity of the solvent. Similarly the strength of a strong base is leveled by the acidity of the solvent. When a strong acid is dissolved in water, it reacts with it to form hydronium ion (H3O+) in the following reaction:[1]
- HCl + H2O → Cl- + H3O+
Any acid that is stronger than H3O+ reacts with H2O to form H3O+. Therefore, no acid stronger than H3O+ exists in H2O. Similarly, when ammonia is the solvent, the strongest acid is ammonium (NH4+), thus HCl and a super acid exert the same acidifying effect.
The same argument applies to bases. In water, OH- is the strongest base. Thus, even though sodium amide (NaNH2) is an exceptional base (pKa of NH3 ~ 33), in water it is only as good as sodium hydroxide. On the other hand, NaNH2 is a far more basic reagent in ammonia than is NaOH.
Leveling and differentiating solvents
In a differentiating solvent, various acids dissociate to different degrees and thus have different strengths. In a leveling solvent, several acids are completely dissociated and are thus of the same strength. A weakly basic solvent has less tendency than a strongly basic one to accept a proton. Similarly a weak acid has less tendency to donate protons than a strong acid. As a result a strong acid such as perchloric acid exhibits more strongly acidic properties than a weak acid such as acetic acid when dissolved in a weakly basic solvent. On the other hand, all acids tend to become indistinguishable in strength when dissolved in strongly basic solvents owing to the greater affinity of strong bases for protons. This is called the leveling effect. Strong bases are leveling solvents for acids, weak bases are differentiating solvents for acids. Because of the leveling effect of common solvents, studies on super acids are conducted in solvents that are very weakly basic such as sulfur dioxide (liquefied) and SO2ClF.[2]
See also
References
- ^ Zumdahl, S. S. “Chemistry” Heath, 1986: Lexington, MA. ISBN: 0-669--04529-2.
- ^ Olah, G. A. (2001). "Hydrogen Fluoride–Antimony(V) Fluoride". In Paquette, L. (ed.). Encyclopedia of Reagents for Organic Synthesis. New York: J. Wiley & Sons. doi:10.1002/047084289X.rh037m.
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