Caesium hexafluorocobaltate(IV)
Caesium hexafluorocobaltate(IV) is a rare example of cobalt(IV) complexs with the chemical formula Cs
2CoF
6. It can be synthesized by the reaction of Cs
3[(CoCl
4)Cl] and fluorine.[1]
It has cubic K2PtCl6 structure, with the lattice constant a = 8.91 Å, and the length of Co-F bond is 1.73 Å. Its ferromagnetic is complex and the ground state of Co(IV) is 2T2.[2]
See also
References
- ^ 张青莲. 《无机化学丛书》第九卷：锰分族、铁系、铂系. 北京: 科学出版社. pp. P333. ISBN 7-03-002238-6.
- ^ Complex Fluorides of Tetravalent Cobalt, J. W. Quail, G. A. Rivett, Canadian Journal of Chemistry, 1972, 50:(15) 2447-2450, 10.1139/v72-394
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