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Coster–Kronig transition

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This is an old revision of this page, as edited by AtomLaurent (talk | contribs) at 00:26, 10 November 2022 (Described why the CK transition is not allowed for free atoms.). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

The Coster–Kronig transition is a special case of the Auger process in which the vacancy is filled by an electron from a higher subshell of the same shell. If, in addition, the electron emitted (the "Auger electron") also belongs to the same shell, one calls this a super Coster–Kronig transition.

Additionally, these transitions only occur in solid-state systems and are forbidden for free atoms. This is connected to the fact that the total angular momentum j for a free atom is still a good quantum number.

The Coster–Kronig process is named after the physicists Dirk Coster and Ralph Kronig.

References

  • Coster, D.; R. De L. Kronig (1935). "New type of Auger effect and its influence on the x-ray spectrum". Physica. 2 (1–12): 13–24. Bibcode:1935Phy.....2...13C. doi:10.1016/S0031-8914(35)90060-X. ISSN 0031-8914.